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EN 14792:2017

Current

Current

The latest, up-to-date edition.

Stationary source emissions - Determination of mass concentration of nitrogen oxides - Standard reference method: chemiluminescence

Published date

01-11-2017

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European foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Symbols and abbreviations
5 Principle
6 Description of the measuring system
7 Performance characteristics of the SRM
8 Suitability of the measuring system to the measurement task
9 Field operation
10 Ongoing quality control
11 Expression of results
12 Equivalence of an alternative method
13 Measurement report
Annex A (informative) - Validation of the method in the field
Annex B (informative) - Sampling and conditioning configurations
Annex C (normative) - Determination of conversion efficiency
Annex D (informative) - Examples of different types of converters
Annex E (informative) - Calculation of the uncertainty associated
        with a concentration expressed for dry gas and
        at an oxygen reference concentration
Annex F (informative) - Example of assessment of compliance
        of chemiluminescence method for NO[x] with
        requirements on emission measurements
Annex G (informative) - Example of correction of data from
        drift effect
Annex H (informative) - Significant technical changes
Bibliography

This European Standard specifies the standard reference method (SRM) based on the chemiluminescence principle for the determination of the nitrogen oxides (NOx) in flue gases emitted to the atmosphere from ducts and stacks. It includes the sampling and the gas conditioning system, as well as the analyser. This European Standard specifies the characteristics to be determined and the performance criteria to be fulfilled by measuring systems based on this measurement method. It applies for periodic monitoring and for the calibration or control of automatic measuring systems (AMS) permanently installed on a stack, for regulatory or other purposes. This European Standard specifies criteria for demonstration of equivalence of an alternative method to the SRM by application of prEN 14793.This European standard has been validated during field tests on waste incineration, co-incineration and large combustion installations and on a recognized test-bench. It has been validated for sampling periods of 30 min in the range of 0 mg/m3 to 1 300 mg/m3 of NO2 for large combustion plants and 0 mg/m3 to 400 mg/m3 of NO2 for waste incineration, according to emission limit values (ELV) laid down in the Directive 2010/75/EC.The ELV for NOx (NO + NO2) in EU directives are expressed in mg/m3 of NO2 on a dry basis, at a specified value for oxygen and at reference conditions (273 K and 101,3 kPa).NOTE The characteristics of installations, the conditions during field tests and the values of repeatability and reproducibility in the field are given in Annex F.

Committee
CEN/TC 264
DevelopmentNote
Supersedes PREN 14792. (01/2017)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

Standards Relationship
UNI EN 14792:2017 Identical
UNE-EN 14792:2017 Identical
NF EN 14792 : 2017 Identical
BS EN 14792:2017 Identical
I.S. EN 14792:2017 Identical
NBN EN 14792 : 2006 Identical
DIN EN 14792:2006-04 Identical
UNI EN 14792 : 2006 Identical
PN EN 14792 : 2017 Identical
SN EN 14792 : 2017 Identical
NS EN 14792 : 2017 Identical
BS EN 14792:2005 Identical
NEN EN 14792 : 2017 Identical
DIN EN 14792:2017-05 Identical

PREN 14181 : DRAFT 2012 STATIONARY SOURCE EMISSIONS - QUALITY ASSURANCE OF AUTOMATED MEASURING SYSTEMS
DIN EN 16738:2016-04 EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
PD CEN/TR 15983:2010 Stationary source emissions. Guidance on the application of EN 14181:2004
UNI EN ISO 21258 : 2010 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF DINITROGEN MONOXIDE (N[2]O) - REFERENCE METHOD: NON-DISPERSIVE INFRARED METHOD
I.S. EN 16738:2015 EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
BS EN 303-5:2012 Heating boilers Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW. Terminology, requirements, testing and marking
CEN/TR 15983:2010 Stationary source emissions - Guidance on the application of EN 14181:2004
DIN EN ISO 21258:2010-11 Stationary source emissions - Determination of the mass concentration of dinitrogen monoxide (N<(Index)2>O) - Reference method: Non-dispersive infrared method (ISO 21258:2010)
BS EN 16738:2015 Emission safety of combustible air fresheners. Test methods
DIN EN 15267-4:2015-08 (Draft) AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
PREN 303-5 : DRAFT 2010 CENTRAL-HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, HAND AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
DIN EN 303-5:2012-10 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
I.S. EN 303-5:2012 HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, MANUALLY AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
VDI 3890:2016-03 Emission control - Pet cremation facilities
VDI 3461:2016-09 (Draft) Emission control - Thermochemical gasification of biomass in cogeneration
VDI 3460 Blatt 1:2014-02 Emission control - Thermal waste treatment - Fundamentals
VDI 3469 Blatt 6:2008-01 Emission control - Production and processing of fibrous materials - Mineral wool insulating materials
VDI 3476 Blatt 1:2015-06 Waste gas cleaning - Methods of catalytic waste gas cleaning - Fundamentals
VDI 2441:2016-05 Process gas and waste gas cleaning by cold plasma - Barrier discharge, corona discharge, UV radiation
VDI 3469 Blatt 4:2008-11 Emission control - Production and processing of fi-brous materials - Friction linings
VDI 3899 Blatt 1:2016-05 Emission control - Landfill gas - Utilisation and treatment of landfill gas
VDI 2447:2011-04 Emission control - Plants to the production and processing of acrylonitrile (AN)
VDI 3896:2015-10 Emission control - Preparation of biogas to natural gas quality
VDI 2576:2010-01 Emission control - Carbothermic and metallothermic production of ferroalloys and silicon metal
VDI 3892:2015-03 Emission control - Roasted-coffee-producing industry - Plants with a minimum daily output of at least 0,5 tonnes
VDI 2293:2011-09 Emission control - Coal preparation plants including driers
VDI 2578:2017-05 Emission control - Glassworks
VDI 2095 Blatt 1:2011-03 Emission control - Treatment of mineral construction-site and demolition waste - Stationary and mobile demolition waste recycling facilities
VDI 2102 Blatt 1:2007-04 (Draft) Emission control - Secondary copper smelting and refining plants
VDI 3455:2013-08 Emission control - High-volume car body painting plants
VDI 3898:2013-01 Emission control - Plants for dry mechanical, physio-chemical, thermal and biological soil treatment
VDI 2594:2015-09 Emission control - Pulp production in the sugar industry
VDI 2102 Blatt 2:2013-04 Emission control - Copper and copper alloy melting plants
VDI 3475 Blatt 5:2015-10 Emission control - Biological waste treatment facilities - Anaerobic digestion and post-treatment
VDI 3454 Blatt 2:2012-04 Emission control - Claus units - Emission measurement
VDI 3476 Blatt 2:2010-01 Waste gas cleaning - Catalytic waste gas cleaning methods - Oxidative processes
UNE-EN 15267-4:2018 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
14/30298789 DC : 0 BS EN 16738 - EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
BS EN 15267-4:2017 Air quality. Certification of automated measuring systems Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
UNI EN 303-5 : 2012 HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, MANUALLY AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
PREN 16510-1 : DRAFT 2013 RESIDENTIAL SOLID FUEL BURNING APPLIANCES - PART 1: GENERAL REQUIREMENTS AND TEST METHODS
I.S. EN 15267-4:2017 AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
10/30228886 DC : 0 BS EN 303-5 - CENTRAL-HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, HAND AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
UNE-EN 16738:2016 Emission safety of combustible air fresheners - Test methods
EN 303-5:2012 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
BS EN ISO 21258:2010 Stationary source emissions. Determination of the mass concentration of dinitrogen monoxide (N2O). Reference method. Non-dispersive infrared method
UNE-CEN/TR 15983:2011 IN Stationary source emissions - Guidance on the application of EN 14181:2004
08/30158227 DC : DRAFT JUNE 2008 BS EN ISO 21258 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF DINITROGEN MONOXIDE - REFERENCE METHOD - NON-DISPERSIVE INFRARED METHOD
S.R. CEN TR 15983:2010 STATIONARY SOURCE EMISSIONS - GUIDANCE ON THE APPLICATION OF EN 14181:2004
I.S. EN ISO 21258:2010 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF DINITROGEN MONOXIDE (N[2]O) - REFERENCE METHOD: NON-DISPERSIVE INFRARED METHOD
13/30271701 DC : 0 BS EN 16510-1 - RESIDENTIAL SOLID FUEL BURNING APPLIANCES - PART 1: GENERAL REQUIREMENTS AND TEST METHODS
PREN 16738 : DRAFT 2014 EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
S.R. CWA 16060:2009 ENVIRONMENTAL TECHNOLOGY VERIFICATION - AIR EMISSION ABATEMENT TECHNOLOGIES
DIN EN 13725:2003-07 Air quality - Determination of odour concentration by dynamic olfactometry
ISO 21258:2010 Stationary source emissions — Determination of the mass concentration of dinitrogen monoxide (N2O) — Reference method: Non-dispersive infrared method
EN 16738:2015 Emission safety of combustible air fresheners - Test methods
EN ISO 21258:2010 Stationary source emissions - Determination of the mass concentration of dinitrogen monoxide (N2O) - Reference method: Non-dispersive infrared method (ISO 21258:2010)
EN 15267-4:2017 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
12/30259213 DC : 0 BS EN 14181 - STATIONARY SOURCE EMISSIONS - QUALITY ASSURANCE OF AUTOMATED MEASURING SYSTEMS
UNE-EN ISO 21258:2010 Stationary source emissions - Determination of the mass concentration of dinitrogen monoxide (N2O) - Reference method: Non-dispersive infrared method (ISO 21258:2010)
UNE-CWA 16060:2010 IN Environmental technology verification - Air emission abatement technologies
UNE-EN 303-5:2013 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
NS-EN 15267-4:2023 Air quality - Assessment of air quality monitoring equipment - Part 4: Performance criteria and test procedures for portable automated measuring systems for periodic measurements of emissions from stationary sources

ISO 14956:2002 Air quality — Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
EN 15259:2007 Air quality - Measurement of stationary source emissions - Requirements for measurement sections and sites and for the measurement objective, plan and report
ISO/IEC Guide 99:2007 International vocabulary of metrology Basic and general concepts and associated terms (VIM)
EN 13284-1:2017 Stationary source emissions - Determination of low range mass concentration of dust - Part 1: Manual gravimetric method
EN ISO 14956:2002 Air quality - Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956:2002)
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
EN 14790:2017 Stationary source emissions - Determination of the water vapour in ducts - Standard reference method
EN 15267-4:2017 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
ISO/IEC Guide 98-3:2008 Uncertainty of measurement — Part 3: Guide to the expression of uncertainty in measurement (GUM:1995)
EN 14793:2017 Stationary source emissions - Demonstration of equivalence of an alternative method with a reference method

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