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EN 14789:2017

Current

Current

The latest, up-to-date edition.

Stationary source emissions - Determination of volume concentration of oxygen - Standard reference method: Paramagnetism

Published date

01-11-2017

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European foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Symbols and abbreviations
5 Principle
6 Description of the measuring system
7 Performance characteristics of the SRM
8 Suitability of the measuring system for the measurement task
9 Field operation
10 Ongoing quality control
11 Expression of results
12 Equivalence of an alternative method
13 Measurement report
Annex A (informative) - Validation of the method in the field
Annex B (informative) - Example of assessment of compliance
        of paramagnetic method for oxygen with given uncertainty
        requirements
Annex C (informative) - Schematic diagram of the measuring system
Annex D (informative) - Example of correction of data from drift
        effect
Annex E (informative) - Significant technical changes
Bibliography

This European Standard specifies the standard reference method (SRM) based on the paramagnetic principle for the determination of the oxygen concentrations in flue gases emitted to the atmosphere from ducts and stacks. It includes the sampling and the gas conditioning system as well as the analyser. This European Standard specifies the performance characteristics to be determined and the performance criteria to be fulfilled by measuring systems based on this measurement method. It applies to periodic monitoring and the calibration or control of automated measuring systems (AMS) permanently installed on a stack, for regulatory or other purposes. This European Standard specifies criteria for demonstration of equivalence of an alternative method (AM) to the SRM by application of prEN 14793.This European Standard has been validated during field tests on waste incineration, co-incineration and large combustion plants and on a recognized test bench. It has been validated for sampling periods of 30 min in the range from 3 % to 21 %. Oxygen concentration values, expressed as volume concentrations, are used to allow results of emission measurements to be standardised to the oxygen reference concentration and dry gas conditions required e.g. by EU Directive 2010/75/EC on industrial emissions. NOTEThe characteristics of installations, the conditions during field tests and the values of repeatability and reproducibility in the field are given in Annex A.

Committee
CEN/TC 264
DevelopmentNote
Supersedes PREN 14789. (01/2017)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

Standards Relationship
UNI EN 14789:2017 Identical
NBN EN 14789 : 2006 Identical
NS EN 14789 : 2017 Identical
NF EN 14789 : 2017 Identical
UNE-EN 14789:2017 Identical
UNI EN 14789 : 2006 Identical
PN EN 14789 : 2017 Identical
SN EN 14789 : 2017 Identical
BS EN 14789:2005 Identical
NEN EN 14789 : 2017 Identical
I.S. EN 14789:2017 Identical
DIN EN 14789:2006-04 Identical
UNE-EN 14789:2006 Identical
BS EN 14789:2017 Identical
DIN EN 14789:2017-05 Identical

DIN EN 16738:2016-04 EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
11/30239461 DC : 0 BS EN ISO 16911-1 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF VELOCITY AND VOLUMETRIC FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD
I.S. EN ISO 16911-1:2013 STATIONARY SOURCE EMISSIONS - MANUAL AND AUTOMATIC DETERMINATION OF VELOCITY AND VOLUME FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD (ISO 16911-1:2013)
I.S. EN 16738:2015 EMISSION SAFETY OF COMBUSTIBLE AIR FRESHENERS - TEST METHODS
BS EN 303-5:2012 Heating boilers Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW. Terminology, requirements, testing and marking
I.S. EN 12619:2013 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
EN 12619:2013 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
BS EN 16738:2015 Emission safety of combustible air fresheners. Test methods
DIN EN 15267-4:2015-08 (Draft) AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
PREN 12619 : DRAFT 2011 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
11/30238654 DC : 0 BS EN 12619 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
14/30303591 DC : 0 BS EN ISO 19694-1 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF GREENHOUSE GAS (GHG) EMISSIONS IN ENERGY-INTENSIVE INDUSTRIES - PART 1: GENERAL ASPECTS
BS EN ISO 11771:2010 Air quality. Determination of time-averaged mass emissions and emission factors. General approach
PREN 303-5 : DRAFT 2010 CENTRAL-HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, HAND AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
DIN EN 12619:2013-04 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
DIN EN 303-5:2012-10 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
I.S. EN 1948-1:2006 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 1: SAMPLING OF PCDDS/PCDFS
DIN EN 1948-1:2006-06 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
I.S. EN 303-5:2012 HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, MANUALLY AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
VDI 3890:2016-03 Emission control - Pet cremation facilities
VDI 3461:2016-09 (Draft) Emission control - Thermochemical gasification of biomass in cogeneration
VDI 2286 Blatt 1:2013-08 Emission control - Electrolytic aluminium reduction process
VDI 3460 Blatt 1:2014-02 Emission control - Thermal waste treatment - Fundamentals
VDI 2283:2008-06 Emission control - Preparation plants for ready-mix asphalt (asphalt mixing plants)
VDI 3476 Blatt 1:2015-06 Waste gas cleaning - Methods of catalytic waste gas cleaning - Fundamentals
VDI 2441:2016-05 Process gas and waste gas cleaning by cold plasma - Barrier discharge, corona discharge, UV radiation
VDI 3891:2015-07 Emission control - Human cremation facilities
VDI 3899 Blatt 1:2016-05 Emission control - Landfill gas - Utilisation and treatment of landfill gas
VDI 2447:2011-04 Emission control - Plants to the production and processing of acrylonitrile (AN)
VDI 2576:2010-01 Emission control - Carbothermic and metallothermic production of ferroalloys and silicon metal
VDI 3457:2016-06 Emission control - Powder coating
VDI 3469 Blatt 1:2016-09 Emission control - Production and processing of fibrous materials - Fibrous dusts; Fundamentals, overview
VDI 2578:2017-05 Emission control - Glassworks
VDI 2095 Blatt 1:2011-03 Emission control - Treatment of mineral construction-site and demolition waste - Stationary and mobile demolition waste recycling facilities
VDI 3455:2013-08 Emission control - High-volume car body painting plants
VDI 3898:2013-01 Emission control - Plants for dry mechanical, physio-chemical, thermal and biological soil treatment
VDI 3475 Blatt 5:2015-10 Emission control - Biological waste treatment facilities - Anaerobic digestion and post-treatment
VDI 3476 Blatt 2:2010-01 Waste gas cleaning - Catalytic waste gas cleaning methods - Oxidative processes
VDI 3477:2016-03 Biological waste gas purification - Biofilters
08/30161739 DC : DRAFT MAY 2008 BS EN ISO 11771 - AIR QUALITY - DETERMINATION OF TIME-AVERAGED MASS EMISSIONS AND EMISSION FACTORS - GENERAL APPROACH
UNE-EN 15267-4:2018 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
11/30243100 DC : 0 BS EN 13649 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF INDIVIDUAL GASEOUS ORGANIC COMPOUNDS - ACTIVATED CARBON AND SOLVENT DESORPTION METHOD
BS EN 15267-4:2017 Air quality. Certification of automated measuring systems Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
BS ISO 18466:2016 Stationary source emissions. Determination of the biogenic fraction in C O<sub>2</sub> in stack gas using the balance method
UNI EN 303-5 : 2012 HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, MANUALLY AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
I.S. EN 15267-4:2017 AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
10/30228886 DC : 0 BS EN 303-5 - CENTRAL-HEATING BOILERS - PART 5: HEATING BOILERS FOR SOLID FUELS, HAND AND AUTOMATICALLY STOKED, NOMINAL HEAT OUTPUT OF UP TO 500 KW - TERMINOLOGY, REQUIREMENTS, TESTING AND MARKING
ISO 18466:2016 Stationary source emissions — Determination of the biogenic fraction in CO2 in stack gas using the balance method
UNE-EN 16738:2016 Emission safety of combustible air fresheners - Test methods
UNI EN 12619 : 2013 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
UNI EN ISO 16911-1 : 2013 STATIONARY SOURCE EMISSIONS - MANUAL AND AUTOMATIC DETERMINATION OF VELOCITY AND VOLUME FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD
UNI EN 1948-1 : 2006 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 1: SAMPLING OF PCDDS/PCDFS
EN 303-5:2012 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
DIN EN ISO 11771:2011-04 Air quality - Determination of time-averaged mass emissions and emission factors - General approach (ISO 11771:2010)
PREN 13649 : DRAFT 2011 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF INDIVIDUAL GASEOUS ORGANIC COMPOUNDS - ACTIVATED CARBON AND SOLVENT DESORPTION METHOD
BS EN ISO 16911-1:2013 Stationary source emissions. Manual and automatic determination of velocity and volume flow rate in ducts Manual reference method
UNI EN ISO 11771 : 2011 AIR QUALITY - DETERMINATION OF TIME-AVERAGED MASS EMISSIONS AND EMISSION FACTORS - GENERAL APPROACH
BS EN 12619:2013 Stationary source emissions. Determination of the mass concentration of total gaseous organic carbon. Continuous flame ionisation detector method
UNE-EN 12619:2013 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
ISO 16911-1:2013 Stationary source emissions — Manual and automatic determination of velocity and volume flow rate in ducts — Part 1: Manual reference method
UNE-EN ISO 16911-1:2013 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013)
ISO 11771:2010 Air quality Determination of time-averaged mass emissions and emission factors General approach
EN 16738:2015 Emission safety of combustible air fresheners - Test methods
EN 15267-4:2017 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
EN ISO 16911-1:2013 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013)
EN 1948-1:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
EN ISO 11771:2010 Air quality - Determination of time-averaged mass emissions and emission factors - General approach (ISO 11771:2010)
UNE-EN ISO 11771:2011 Air quality - Determination of time-averaged mass emissions and emission factors - General approach (ISO 11771:2010)
DIN EN ISO 16911-1:2013-06 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013); German version EN ISO 16911-1:2013
16/30275160 DC : 0 BS ISO 18466 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE BIOGENIC FRACTION IN CO[2]IN STACK GAS USING THE BALANCE METHOD
I.S. EN ISO 11771:2010 AIR QUALITY - DETERMINATION OF TIME-AVERAGED MASS EMISSIONS AND EMISSION FACTORS - GENERAL APPROACH
UNE-EN 303-5:2013 Heating boilers - Part 5: Heating boilers for solid fuels, manually and automatically stoked, nominal heat output of up to 500 kW - Terminology, requirements, testing and marking
NS-EN 15267-4:2023 Air quality - Assessment of air quality monitoring equipment - Part 4: Performance criteria and test procedures for portable automated measuring systems for periodic measurements of emissions from stationary sources

ISO 14956:2002 Air quality — Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
EN 15259:2007 Air quality - Measurement of stationary source emissions - Requirements for measurement sections and sites and for the measurement objective, plan and report
ISO/IEC Guide 99:2007 International vocabulary of metrology Basic and general concepts and associated terms (VIM)
EN ISO 14956:2002 Air quality - Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956:2002)
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
EN 14790:2017 Stationary source emissions - Determination of the water vapour in ducts - Standard reference method
EN 15267-4:2017 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
ISO/IEC Guide 98-3:2008 Uncertainty of measurement — Part 3: Guide to the expression of uncertainty in measurement (GUM:1995)
EN 14793:2017 Stationary source emissions - Demonstration of equivalence of an alternative method with a reference method

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