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EN 15192:2006

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by

Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection

Superseded date

15-07-2021

Superseded by

EN ISO 15192:2021

Published date

15-11-2006

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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and Definitions
4 Safety remarks
5 Principle
6 Apparatus
7 Reagents
8 Sample pretreatment
9 Alkaline digestion procedure
10 Analytical procedure
11 Calculation
12 Expression of results
13 Test report
Annex A (informative) Alternative methods for direct
        determination of Cr(VI) in the alkaline digestion
        solution
Annex B Ion chromatographic system
Annex C (informative) Requirements for test portion
        preparation
Annex D (informative) Background on methods for the
        determination of Cr(VI) in solid samples
   D.1 Summary of literature methods for Cr(VI)
        determinations in solids [6]
   D.2 Theoretical kinetic background for Cr(III)-Cr(VI)
        inter-conversions [6]
   D.3 Special needs for Cr(VI) determination in soil
        extracts [7]
   D.4 Determination of Cr(VI) in glass
   D.5 Determination of Cr(VI) in air particulate matter
Annex E (informative) Validation
Bibliography

This standard describes the determination of Cr(VI) in solid waste material and soil by alkaline digestion and ion chromatography with spectrophotometric detection. This method can be used to determine Cr(VI)-mass fractions in solids higher than 0,1 mg/kg.

Committee
CEN/TC 444
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded
SupersededBy

Standards Relationship
UNE-EN 15192:2007 Identical
NS EN 15192 : 1ED 2006 Identical
NBN EN 15192 : 2006 Identical
PN EN 15192 : 2006 Identical
I.S. EN 15192:2006 Identical
NEN EN 15192 : 2006 Identical
NF EN 15192 : 2007 Identical
SN EN 15192 : 2007 Identical
BS EN 15192:2006 Identical
UNI EN 15192 : 2007 Identical
ONORM EN 15192 : 2007 Identical
DIN EN 15192:2007-02 Identical

DIN EN 16318:2016-07 FERTILIZERS AND LIMING MATERIALS - DETERMINATION OF CHROMIUM(6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
CEN/TS 16318:2012 Fertilizers - Determination of trace elements - Determination of chromium(VI) by photometry (method A) and by ion chromatography with spectrophotometric detection (method B)
UNI EN 16457 : 2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
I.S. EN 16457:2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
S.R. CEN/TS 16318:2012 FERTILIZERS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF CHROMIUM(6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
17/30348303 DC : 0 BS EN 17087 - CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE FOR TESTING OF RELEASE AND ANALYSIS OF CONTENT
UNE-EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
I.S. EN 15002:2015 CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
13/30276853 DC : 0 BS EN 16318 - FERTILIZERS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF CHROMIUM (6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
UNE-EN 16457:2014 Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report
UNI CEN/TS 16318 : 2012 FERTILIZERS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF CHROMIUM (6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
12/30263896 DC : 0 BS EN 16457 - CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
BS ISO 18512:2007 Soil quality. Guidance on long and short term storage of soil samples
DIN ISO 18512:2009-03 SOIL QUALITY - GUIDANCE ON LONG AND SHORT TERM STORAGE OF SOIL SAMPLES
DIN EN 16457:2014-07 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
I.S. EN 16318:2013 FERTILIZERS AND LIMING MATERIALS - DETERMINATION OF CHROMIUM(6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
BS EN 16318 : 2013 FERTILIZERS AND LIMING MATERIALS - DETERMINATION OF CHROMIUM(6) BY PHOTOMETRY (METHOD A) AND BY ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION (METHOD B)
ISO 18512:2007 Soil quality Guidance on long and short term storage of soil samples
13/30291099 DC : 0 BS EN 15002 - CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
DIN EN 15002:2015-07 CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
EN 16457:2014 Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report
DIN EN 16457 E : 2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
PD CEN/TS 16318:2012 Fertilizers. Determination of trace elements. Determination of chromium(VI) by photometry (method A) and by ion chromatography with spectrophotometric detection (method B)
BS EN 16457:2014 Characterization of waste. Framework for the preparation and application of a testing programme. Objectives, planning and report
BS EN 15002:2015 Characterization of waste. Preparation of test portions from the laboratory sample
EN 16318:2013+A1:2016 Fertilizers and liming materials - Determination of chromium(VI) by photometry (method A) and by ion chromatography with spectrophotometric detection (method B)
UNE-EN 16318:2015 Fertilizers - Determination of trace elements - Determination of chromium(VI) by photometry (method A) and by ion chromatography with spectrophotometric detection (method B)

ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
PREN 14346 : DRAFT 2004 CHARACTERIZATION OF WASTE - CALCULATION OF DRY MATTER BY DETERMINATION OF DRY RESIDUE AND WATER CONTENT
EN ISO 11885:2009 Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007)
CEN/TR 14589:2003 Characterization of waste - State of the art document - Chromium VI specification in solid matrices
ISO 11083:1994 Water quality — Determination of chromium(VI) — Spectrometric method using 1,5-diphenylcarbazide
EN ISO 15586:2003 Water quality - Determination of trace elements using atomic absorption spectrometry with graphite furnace (ISO 15586:2003)
ISO 11464:2006 Soil quality Pretreatment of samples for physico-chemical analysis
ISO 10304-3:1997 Water quality — Determination of dissolved anions by liquid chromatography of ions — Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate
ISO 11885:2007 Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES)
ISO 16740:2005 Workplace air Determination of hexavalent chromium in airborne particulate matter Method by ion chromatography and spectrophotometric measurement using diphenyl carbazide
ISO 15586:2003 Water quality — Determination of trace elements using atomic absorption spectrometry with graphite furnace
ISO 5725:1986 Precision of test methods Determination of repeatability and reproducibility for a standard test method by inter-laboratory tests
ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
EN 12506:2003 Characterization of waste - Analysis of eluates - Determination of pH, As, Ba, Cd, Cl-, Co, Cr, Cr Vl, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn
ISO 17294-2:2016 Water quality — Application of inductively coupled plasma mass spectrometry (ICP-MS) — Part 2: Determination of selected elements including uranium isotopes
EN ISO 17294-2:2016 Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of selected elements including uranium isotopes (ISO 17294-2:2016)

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