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ASTM D 2036 : 2009 : R2022

Current

Current

The latest, up-to-date edition.

Standard Test Methods for Cyanides in Water

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

13-05-2022

£52.98
Excluding VAT

Committee
D 19
DocumentType
Test Method
Pages
20
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1These test methods cover the determination of cyanides in water. The following test methods are included:

Sections

Test Method A
 Total Cyanides after Distillation

12 – 18

Test Method B
 Cyanides Amenable to Chlorination2
 by Difference

19 – 25

Test Method C
 Weak Acid Dissociable Cyanides

26 – 32

Test Method D
 Cyanides Amenable to Chlorination without
 Distillation (Short-Cut Method)

33 – 39

1.2Cyanogen halides may be determined separately.

Note 1:Cyanogen chloride is the most common of the cyanogen halide complexes as it is a reaction product and is usually present when chlorinating cyanide-containing industrial waste water. For the presence or absence of CNCl, the spot test method given in Annex A1 can be used.

1.3These test methods do not distinguish between cyanide ions and metallocyanide compounds and complexes. Furthermore, they do not detect the cyanates. Cyanates can be determined using ion chromatography without digestion.

Note 2:The cyanate complexes are decomposed when the sample is acidified in the distillation procedure.

1.4The cyanide in cyanocomplexes of gold, platinum, cobalt and some other transition metals is not completely recovered by these test methods. Refer to Test Method D6994 for the determination of cyanometal complexes.

1.5Cyanide from only a few organic cyanides are recovered, and those only to a minor extent.

1.6Part or all of these test methods have been used successfully with reagent water and various waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.

1.7The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.8This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in 5.1, 8.8, 8.18, Section 9, 11.3, and 16.1.9.

1.9This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D 7572 : 2015 : R2022 Standard Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil
ASTM D 4165 : 2006 : R2020 : EDT 1 Standard Test Method for Cyanogen Chloride in Water
ASTM D 4193 : 2008 : R2020 : EDT 1 Standard Test Method for Thiocyanate in Water
ASTM D 7511 : 2012 : R2017 : EDT 1 Standard Test Method for Total Cyanide by Segmented Flow Injection Analysis, In-Line Ultraviolet Digestion and Amperometric Detection
ASTM D 7284 : 2020 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM D 7237 : 2018 Standard Test Method for Free Cyanide and Aquatic Free Cyanide with Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM E 800 : 2020 Standard Guide for Measurement of Gases Present or Generated During Fires
ASTM D 7295 : 2018 Standard Practice for Sampling Combustion Effluents and Other Stationary Sources for the Subsequent Determination of Hydrogen Cyanide
ASTM D 7728 : 2018 Standard Guide for Selection of ASTM Analytical Methods for Implementation of International Cyanide Management Code Guidance
ASTM D 3694 : 1996 : R2017 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D 6888 : 2016 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection

ASTM D 5788 : 1995 : R2017 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
ASTM D 1129 : 2013 : R2020 : EDT 2 Standard Terminology Relating to Water
ASTM D 6696 : 2016 Standard Guide for Understanding Cyanide Species
ASTM D 2777 : 2021 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1129 : 2013 : R2020 : EDT 1 Standard Terminology Relating to Water
ASTM E 60 : 2011 : R2016 Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
ASTM D 5847 : 2002 : R2020 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 5788 : 1995 : R2024 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 6888 : 2016 : R2023 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 6696 : 2016 : R2023 Standard Guide for Understanding Cyanide Species
ASTM D 5847 : 2022 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 7365 : 2009 : REV A : R2015 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM E 60 : 2011 : R2022 : EDT 1 Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
ASTM D 6994 : 2015 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection (Withdrawn 2024)
ASTM D 7365 : 2009 : REV A : R2022 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide

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