EN 12457-4:2002
Current
The latest, up-to-date edition.
Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction)
18-09-2002
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
3.1 Leaching test
3.2 Leachant
3.3 Eluate
3.4 Single batch leaching test
3.5 Serial batch leaching test
3.6 Liquid to solid ratio L/S (abbreviation: L/S)
3.7 Liquid waste
3.8 Sludge
3.9 Monolithic waste
3.10 Granular waste
3.11 Dry matter content ratio (abbreviation: DR)
3.12 Moisture content ratio (abbreviation MC)
3.13 Laboratory sample
3.14 Test sample
3.15 Test portion
4 Compliance test
4.1 Principle
4.2 Equipment and reagents
4.3 Sampling strategy and sample preparation
5 Procedure
5.1 Testing conditions
5.2 Description of the procedure
5.3 Further preparation of the eluate for analysis
5.4 Blank test for the verification of the leaching
procedure
6 Calculation
7 Documentation and test report
7.1 Sample preparation
7.2 Production of eluate
7.3 Analytical determination
7.4 Calculations and blank test information
8 Performance characteristics
8.1 Objective of the validation
8.2 Validation study
8.3 Validation results
8.4 Summary of the performance characteristics evaluation
Annex A (informative) Information on the influence on the
test results of the parameters that effect leaching
Annex B (informative) Test for determining whether waste is
in the liquid state
Annex C (informative) Example of datasheet for EN 12457-4
Annex D (informative) Process map for EN 12457-4
Annex E (informative) Example of a specific liquid-solid
separation procedure for soil sample
Annex ZA (informative) National deviation A from France
Bibliography
This part of the European Standard specifies a compliance test providing information on leaching of granular wastes and sludges under the experimental conditions specified hereafter, and particularly a liquid to solid ratio of 10 l/kg dry matter. It applies to waste which has a particle size below 10 mm without or with limited size reduction. Note: In some cases, it could be useful to test the material with coarser particles up to 40 mm in diameter: This requires a larger amount for material and liquid.
Committee |
CEN/TC 444
|
DocumentType |
Standard
|
PublisherName |
Comite Europeen de Normalisation
|
Status |
Current
|
Standards | Relationship |
UNE-EN 12457-4:2003 | Identical |
NF EN 12457-4 : 2002 | Identical |
SN EN 12457-4 : 2002 | Identical |
NS EN 12457-4 : 1ED 2003 | Identical |
NBN EN 12457-4 : 2002 | Identical |
NEN EN 12457-4 : 2002 | Identical |
PN EN 12457-4 : 2006 | Identical |
UNI EN 12457-4 : 2004 | Identical |
DIN EN 12457-4:2003-01 | Identical |
I.S. EN 12457-4:2002 | Identical |
BS EN 12457-4:2002 | Identical |
DIN EN 14405:2017-05 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS) |
I.S. EN 12506:2003 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF PH, AS, BA, CD, CL[-], CO, CR, CR (6), CU, MO, NI, NO[2-], PB, TOTAL S, SO[4][2-], V AND ZN |
BS EN 14405:2017 | Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions) |
14/30304804 DC : 0 | BS EN 14405 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS) |
I.S. EN 14405:2017 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS) |
PD CEN/TR 16376:2012 | Characterization of waste. Overall guidance document for characterization of waste from the extractive industries |
DIN EN 15863:2015-06 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED CONDITIONS |
DIN EN 12506:2003-09 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF PH, AS, BA, CD, CI[-], CO, CR, CR(VI), CU, MO, NI, NO[2-], PB, TOTAL S, SO[4][2-], V AND ZN |
EN 12506:2003 | Characterization of waste - Analysis of eluates - Determination of pH, As, Ba, Cd, Cl-, Co, Cr, Cr Vl, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn |
CEN/TR 16376:2012 | Characterization of waste - Overall guidance document for characterization of waste from the extractive industries |
EN 14405:2017 | Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions) |
EN 15863:2015 | Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions |
UNI EN 16457 : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
10/30233988 DC : 0 | BS EN 16192 - CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES |
UNI EN ISO 18772 : 2014 | SOIL QUALITY - GUIDANCE ON LEACHING PROCEDURES FOR SUBSEQUENT CHEMICAL AND ECOTOXICOLOGICAL TESTING OF SOILS AND SOIL MATERIALS |
I.S. EN 16457:2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
CEN/TS 16637-1:2014 | Construction products - Assessment of release of dangerous substances - Part 1: Guidance for the determination of leaching tests and additional testing steps |
PREN 14405 : DRAFT 2014 | CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS) |
UNI CEN/TS 16637-1 : 2014 | CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PART 1: GUIDANCE FOR THE DETERMINATION OF LEACHING TESTS AND ADDITIONAL TESTING STEPS |
UNE-EN 14405:2017 | Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions) |
17/30348303 DC : 0 | BS EN 17087 - CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE FOR TESTING OF RELEASE AND ANALYSIS OF CONTENT |
UNE-EN 15863:2015 | Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions |
UNE-EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
DIN EN 13370:2003-09 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, CN[-] EASILY LIBERATABLE, F[-] |
I.S. EN 15002:2015 | CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
PD CEN/TS 16660:2015 | Characterization of waste. Leaching behaviour test. Determination of the reducing character and the reducing capacity |
BS EN 16192:2011 | Characterization of waste. Analysis of eluates |
BS EN ISO 18772:2014 | Soil quality. Guidance on leaching procedures for subsequent chemical and ecotoxicological testing of soils and soil materials |
UNE-EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
S.R. CEN TR 16110:2010 | CHARACTERIZATION OF WASTE - GUIDANCE ON THE USE OF ECOTOXICITY TESTS APPLIED TO WASTE |
I.S. EN 16192:2011 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES |
PD CEN/TS 16637-1:2014 | Construction products. Assessment of release of dangerous substances Guidance for the determination of leaching tests and additional testing steps |
S.R. CEN/TR 16376:2012 | CHARACTERIZATION OF WASTE - OVERALL GUIDANCE DOCUMENT FOR CHARACTERIZATION OF WASTE FROM THE EXTRACTIVE INDUSTRIES |
S.R. CEN/TS 16637-1:2014 | CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PART 1: GUIDANCE FOR THE DETERMINATION OF LEACHING TESTS AND ADDITIONAL TESTING STEPS |
BS EN 12506:2003 | Characterization of waste. Analysis of eluates. Determination of pH, As, Ba, Cd, Cl<sup>-</sup>, Co, Cr, Cr VI, Cu, Mo, Ni, NO<sub>2</sub><sup>-</sup>, Pb, total S, SO<sub>4</sub><sup>2-</sup>, V and Zn |
I.S. EN 13370:2003 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, EASILY LIBERATABLE CN[-], F[-] |
I.S. EN 15863:2015 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED CONDITIONS |
DIN EN 16192:2012-02 | Characterization of waste - Analysis of eluates |
12/30263896 DC : 0 | BS EN 16457 - CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
FD CEN/TR 16110 : 2011 FD | CHARACTERIZATION OF WASTE - GUIDANCE ON THE USE OF ECOTOXICITY TESTS APPLIED TO WASTE |
DIN EN 16457:2014-07 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
ISO 18772:2008 | Soil quality — Guidance on leaching procedures for subsequent chemical and ecotoxicological testing of soils and soil materials |
13/30291099 DC : 0 | BS EN 15002 - CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
BS EN 15863:2015 | Characterization of waste. Leaching behaviour test for basic characterization. Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions |
BS EN 13370:2003 | Characterization of waste. Analysis of eluates. Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN<sup>-</sup>, F<sup>-</sup> |
DIN EN 15002:2015-07 | CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
EN ISO 18772:2014 | Soil quality - Guidance on leaching procedures for subsequent chemical and ecotoxicological testing of soils and soil materials (ISO 18772:2008) |
EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
13/30286658 DC : 0 | BS EN 16660 - CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - DETERMINATION OF THE REDUCING CHARACTER AND THE REDUCING CAPACITY |
DIN EN 16457 E : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
BS EN 16457:2014 | Characterization of waste. Framework for the preparation and application of a testing programme. Objectives, planning and report |
04/30116791 DC : DRAFT JUL 2004 | BS EN 15002 - CHARACTERISATION OF WASTE - PREPARATION OF TEST PORTIONS FROM LABORATORY SAMPLE |
UNE-EN 16192:2012 | Characterization of waste - Analysis of eluates |
S.R. CEN/TS 16660:2015 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - DETERMINATION OF THE REDUCING CHARACTER AND THE REDUCING CAPACITY |
UNE-CEN/TR 16110:2011 IN | Characterization of waste - Guidance on the use of ecotoxicity tests applied to waste |
BS ISO 18772 : 2008 COR 2014 | SOIL QUALITY - GUIDANCE ON LEACHING PROCEDURES FOR SUBSEQUENT CHEMICAL AND ECOTOXICOLOGICAL TESTING OF SOILS AND SOIL MATERIALS |
I.S. EN ISO 18772:2014 | SOIL QUALITY - GUIDANCE ON LEACHING PROCEDURES FOR SUBSEQUENT CHEMICAL AND ECOTOXICOLOGICAL TESTING OF SOILS AND SOIL MATERIALS (ISO 18772:2008) |
UNI EN 16192 : 2012 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES |
13/30286655 DC : 0 | BS EN 15863 - CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED TEST CONDITIONS |
BS EN 15002:2015 | Characterization of waste. Preparation of test portions from the laboratory sample |
EN 13370:2003 | Characterization of waste - Analysis of eluates - Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN-, F- |
CEN/TR 16110:2010 | Characterization of waste - Guidance on the use of ecotoxicity tests applied to waste |
CEN/TS 16660:2015 | Characterization of waste - Leaching behaviour test - Determination of the reducing character and the reducing capacity |
EN 16192:2011 | Characterization of waste - Analysis of eluates |
ENV 12920 : 1997 | CHARACTERIZATION OF WASTE - METHODOLOGY FOR THE DETERMINATION OF THE LEACHING BEHAVIOUR OF WASTE UNDER SPECIFIED CONDITIONS |
EN 12880:2000 | Characterization of sludges - Determination of dry residue and water content |
ENV 12506 : DRAFT 2000 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF PH, AS, CD, CR (6), CU, NI, PB, ZN, CL[-], NO[2][-], SO[4][2-] |
ISO 5667-3:2012 | Water quality Sampling Part 3: Preservation and handling of water samples |
DIN 38414 : LATEST | |
ENV 13370 : DRAFT 2001 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM - N, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, CN - EASILY LIBERATABLE, F |
EN ISO 5667-3:2012 | Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012) |
ISO 3696:1987 | Water for analytical laboratory use — Specification and test methods |
EN ISO 3696:1995 | Water for analytical laboratory use - Specification and test methods (ISO 3696:1987) |
NFX 31 210 : 1998 | |
NEN 7343 : 1995 | LEACHING CHARACTERISTICS OF SOLID EARTHY AND STONY BUILDING AND WASTE MATERIALS - LEACHING TESTS - DETERMINATION OF THE LEACHING OF INORGANIC COMPONENTS FROM GRANULAR MATERIALS WITH THE COLUMN TEST |
ISO 5725-5:1998 | Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method |
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