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CR 10299:1998

Withdrawn

Withdrawn

A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

Guidelines for the preparation of standard routine methods with wavelength-dispersive X-ray fluorescence spectrometry

Published date

31-12-1998

Withdrawn date

12-03-2025

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1. Purpose of the guideline
2. Principals of the method
3. Terminology - Definitions
4. Instrumentation
5. Sampling and sample preparation
6. Evaluation methods
7. Calibration strategy
8. Validation of method (trueness and precision)
9. Performance Criteria
10. Radiation protection
ANNEX A - Bibliography
ANNEX B - Example of calculation of Background Equivalent
          Concentration (BEC), Limit of Detection (LOD),
          Limit of Quantification (LOQ) and Lower Limit
          of Detection (LLD)
ANNEX C - Example of calculation of line interference of
          molybdenum on phosphorus
ANNEX D - Example of Performance Criteria, precision test
ANNEX E - Example of two computerised SPC-diagrams

X-ray Fluorescence Spectrometry (XRF) has been used for several decades as an important analytical tool for production analysis. XRF is characterised by its speed and high precision over a wide concentration range and since the technique in most cases is used as an relative method the limitations are often connected to the quality of the calibration samples. The technique is well established and most of its physical properties are well known.

Committee
CEN/TC 459/SC 2
DocumentType
Report
PublisherName
Comite Europeen de Normalisation
Status
Withdrawn

Standards Relationship
NEN NPR CR 10299 : 1999 Identical
XP CR 10299 : 99 XP Identical
S.R. CR 10299:1999 Identical

DIN EN 10315:2006-10 Routine method for analysis of high alloy steel by X-ray Fluorescence Spectrometry (XRF) by using a near by technique
13/30288139 DC : 0 BS EN 15063-1 - COPPER AND COPPER ALLOYS - DETERMINATION OF MAIN CONSTITUENTS AND IMPURITIES BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY (XRF) - PART 1: GUIDELINES TO THE ROUTINE METHOD
BS EN 10315:2006 Routine method for analysis of high alloy steel by X-ray fluorescence spectrometry (XRF) by using a near by technique
PREN 15063-1 : DRAFT 2013 COPPER AND COPPER ALLOYS - DETERMINATION OF MAIN CONSTITUENTS AND IMPURITIES BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY (XRF) - PART 1: GUIDELINES TO THE ROUTINE METHOD
08/30190548 DC : DRAFT DEC 2008 BS EN ISO 17054 - ROUTINE METHOD FOR ANALYSIS OF HIGH ALLOY STEEL BY X-RAY FLUORESCENCE SPECTROMETRY (XRF) BY USING A NEAR BY TECHNIQUE
ISO 17054:2010 Routine method for analysis of high alloy steel by X-ray fluorescence spectrometry (XRF) by using a near-by technique
DIN EN 15063-1:2015-03 COPPER AND COPPER ALLOYS - DETERMINATION OF MAIN CONSTITUENTS AND IMPURITIES BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY (XRF) - PART 1: GUIDELINES TO THE ROUTINE METHOD
I.S. EN 15063-1:2014 COPPER AND COPPER ALLOYS - DETERMINATION OF MAIN CONSTITUENTS AND IMPURITIES BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY (XRF) - PART 1: GUIDELINES TO THE ROUTINE METHOD
I.S. EN 10315:2006 ROUTINE METHOD FOR ANALYSIS OF HIGH ALLOY STEEL BY X-RAY FLUORESCENCE SPECTROMETRY (XRF) BY USING A NEAR BY TECHNIQUE
PD CEN/TR 10261:2013 Iron and steel. European standards for the determination of chemical composition
BS EN 15063-1:2014 Copper and copper alloys. Determination of main constituents and impurities by wavelength dispersive X-ray fluorescence spectrometry (XRF) Guidelines to the routine method
EN 15063-1:2014 Copper and copper alloys - Determination of main constituents and impurities by wavelength dispersive X-ray fluorescence spectrometry (XRF) - Part 1: Guidelines to the routine method
CEN/TR 10261:2013 Iron and steel - European standards for the determination of chemical composition
EN 10315:2006 Routine method for analysis of high alloy steel by X-ray Fluorescence Spectrometry (XRF) by using a near by technique
UNE-EN 15063-1:2015 Copper and copper alloys - Determination of main constituents and impurities by wavelength dispersive X-ray fluorescence spectrometry (XRF) - Part 1: Guidelines to the routine method

ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions
ISO 5725-3:1994 Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
ISO 5725-4:1994 Accuracy (trueness and precision) of measurement methods and results — Part 4: Basic methods for the determination of the trueness of a standard measurement method
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method

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