ASTM E 222 : 2017
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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Standard Test Methods for Hydroxyl Groups Using Acetic Anhydride Acetylation
Hardcopy , PDF
13-06-2023
English
22-02-2019
Important note : All end users must be registered with an Account prior to user licenses being assigned.These test methods cover the determination of hydroxyl groups attached to primary and secondary carbon atoms in aliphatic and alicyclic compounds and phenols.
| Committee |
D 16
|
| DocumentType |
Test Method
|
| Pages |
8
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Superseded
|
| SupersededBy | |
| Supersedes |
1.1These test methods cover the determination of hydroxyl groups attached to primary and secondary carbon atoms in aliphatic and alicyclic compounds and phenols.
1.2Three test methods are given as follows:
|
| Sections |
| Test Method A (Pressure Bottle Method) | 8 – 14 |
| Test Method B (Reflux Method) | 16 – 22 |
| Test Method C (Perchloric Acid Catalyzed Method) | 24 – 30 |
1.2.1Test Method A is recommended for general use. Test Method B is included to give a standard procedure for the method that has been used widely. Test Method C is recommended when the results are required in a minimum period of time or where ambient temperature for the reaction is desired.
1.2.2The results obtained using Test Methods A and B will be essentially the same, but the results obtained using Test Method C will be higher (up to approximately 4 % relative) than those obtained using the other two methods.
1.2.3Statements on precision are included with each test method. The precision of Test Methods A and C is consistent over a wide range of hydroxyl content (tested over hydroxyl number range of 250 to 1600), whereas Test Method B is less precise at the higher hydroxyl content level than it is at the lower hydroxyl content level. In general, Test Method A is approximately two-fold as precise as Test Method C. Test Method B has approximately the same precision as Test Method C at the lower hydroxyl content level but poorer precision at the higher hydroxyl content level.
1.2.4The interferences are essentially the same for the three methods. Some compounds can be analyzed using Test Methods A or B but not using Test Method C because of interfering reactions of the strong acid catalyst with the compound being analyzed or the acetate product formed in the determination. However, because of its increased reactivity, Test Method C is applicable for determination of some compounds, particularly sterically hindered secondary alcohols, which react too slowly or not at all in Test Methods A and B.
Note 1:Other methods for determination of hydroxyl groups are given in Test Methods D1957, D2195, E326, E335, and E567.
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4Review the current appropriate Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, and safety precautions.
1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 7.
1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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| ASTM D 4274 : 2023 | Standard Test Methods for Testing Polyurethane Raw Materials: Determination of Hydroxyl Numbers of Polyols |
| ASTM D 2195 : 2000 | Standard Test Methods for Pentaerythritol |
| ASTM D 6809 : 2002 : R2016 | Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
| ASTM D 6809 : 2020 | Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
| ASTM E 567 : 1991 | Test Method for Tertiary Hydroxyl Groups with Hydrogen Bromide (Withdrawn 1996) |
| ASTM D 2195 : 2005 | Standard Test Methods for Pentaerythritol (Withdrawn 2011) |
| ASTM D 1957 : 1986 : R1995 : EDT 1 | Standard Test Method for Hydroxyl Value of Fatty Oils and Acids |
| ASTM D 1193 : 1977 : R1983 : EDT 1 | Standard Specification for Reagent Water |
| ASTM D 1193 : 2006 : R2011 | Standard Specification for Reagent Water |
| ASTM D 6809 : 2002 : R2012 | Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
| ASTM D 1193 : 1991 | Standard Specification for Reagent Water |
| ASTM D 1957 : 1986 : R2001 | Standard Test Method for Hydroxyl Value of Fatty Oils and Acids (Withdrawn 2007) |
| ASTM E 326 : 1996 | Test Method for Hydroxyl Groups by Phthalic Anhydride Esterification (Withdrawn 2001) |
| ASTM D 6809 : 2002 | Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
| ASTM D 1193 : 1970 | Standard Specification For Reagent Water |
| ASTM D 1193 : 2006 | Standard Specification for Reagent Water |
| ASTM D 1193 : 1999 | Standard Specification for Reagent Water |
| ASTM D 6809 : 2002 : R2007 | Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
| ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
| ASTM E 335 : 1996 | Standard Test Method for Hydroxyl Groups by Pyromellitic Dianhydride Esterification (Withdrawn 2003) |
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