ASTM E 1510 : 1995 : R2013 : EDT 1
Superseded
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs
Available format(s)
Hardcopy , PDF
Superseded date
26-04-2021
Superseded by
Language(s)
English
Published date
25-01-2013
Important note : All end users must be registered with an Account prior to user licenses being assigned.CONTAINED IN VOL. 03.06, 2015 Defines the installation and maintenance of fused silica capillary columns in gas chromatographs that are already retrofitted for their use.
| Committee |
E 13
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| DocumentType |
Standard Practice
|
| Pages |
13
|
| ProductNote |
Reconfirmed EDT 1
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Superseded
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| SupersededBy | |
| Supersedes |
1.1This practice covers the installation and maintenance of fused silica capillary columns in gas chromatographs that are already retrofitted for their use. This practice excludes information on:
1.2For additional information on gas chromatography, please refer to Practice E260. For specific precautions, see 7.2.2.2(1), 7.2.2.2(2), 7.2.7, and 7.2.7.2.
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safety information, see Section 6, 7.2.2.2(1), 7.2.2.2(2), 7.2.7, and 7.2.7.2.2
TABLE 1 Typical Splitter Vent Flow Rates (50 to 1 split ratio) (at optimum linear velocity)
| Carrier gas | 0.25-mm ID, | 0.32-mm ID, | 0.53-mm ID, |
| helium | 35 | 80 | 125 |
Note 1—The curves were generated by plotting the height equivalent to a theoretical plate (length of column divided by the total number of theoretical plates, H.E.T.P.) against the column's average linear velocity. The lowest point on the curve indicates the carrier gas velocity in which the highest column efficiency is reached.
Note 2—Gases information available from Compressed Gas Association (CGA), 4221 Walney Rd., 5th Floor, Chantilly, VA 20151-2923, http://www.cganet.com.
FIG. 1Van Deemter Profile for Hydrogen, Helium, and Nitrogen Carrier Gases
Note 1—Fig. 2 shows that the resolution is similar but the analysis time is reduced by 50 % when comparing hydrogen to helium in an isothermal analysis using optimum flow velocities.
Note 2—Hydrogen provides similar resolution in one-half the analysis time of helium for an isothermal analysis.
Note 4—30 m, 0.25-mm ID, 0.25 μm 5 % diphenyl − 95 % dimethyl polysiloxane 0.1-μL split injection of chlorinated pesticides.
| Oven temperature: 210°C isothermal | |
| Injector and detector temperature: 250°C/300°C | |
| ECD sensitivity: 512 × 10 −11 | |
| Split vent: 100 cm 3 /min |
FIG. 2Hydrogen Versus Helium (Isothermal Analysis)
Note 1—Septum bleed can obscure or co-elute with compounds of interest, thus decreasing the analytical accuracy.
Note 2—
| 1.2,4,5,6-tetrachloro- | 8.Heptachlor | 16.p,p-DDD | |
| m-xylene (IS) | epoxide | 17.Endrin aldehyde | |
| 2.α-BHC | 9.γ-chlordane | 18.Endosulfan sul- | |
| 3.β-BHC | 10.Endosulfan I | fate | |
| 4.γ-BHC | 11.α-chlordane | 19.p,p-DDT | |
| 5.δ-BHC | 12.Dieldrin | 20.Endrin ketone | |
| 6.Heptachlor | 13.p,p-DDE | 21.Methyoxychlor | |
| 7.Aldrin | 14.Endrin | 22.Decachlorobi- | |
| 15.Endosulfan II | phenyl (IS) |
Note 3—30 m, 0.53-mm ID, 0.50 μm 5 % diphenyl − 95 % dimethyl polysiloxane 0.1 μL direct injection of 50 pg pesticide standard.
| Oven temperature: 150 to 275°C at 4°C/min, | |
| Injector temperature: 250°C | Detector temperature: 300°C |
| Carrier gas: Helium | |
| Linear velocity: 40 cm/s (Flow rate: 10 cm 3 /min) | |
| ECD sensitivity: 8 × 10 −11 AFS |
FIG. 4ECD Septum Bleed
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