ASTM C 697 : 2016 : REDLINE
Current
The latest, up-to-date edition.
Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Plutonium Dioxide Powders and Pellets
English
01-06-2016
Important note : All end users must be registered with an Account prior to user licenses being assigned.CONTAINED IN VOL. 12.01, 2016 Gives procedures for the chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets to determine compliance with specifications.
| Committee |
C 26
|
| DocumentType |
Redline
|
| Pages |
38
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
1.1These test methods cover procedures for the chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets to determine compliance with specifications.
1.2The analytical procedures appear in the following order:
| Sections | |
| Plutonium Sample Handling | 8 to 10 |
| Plutonium by Controlled-Potential Coulometry | 2 |
| Plutonium by Ceric Sulfate Titration | 3 |
| Plutonium by Amperometric Titration with Iron(II) | 2 |
| Plutonium by Diode Array Spectrophotometry | 3 |
| Nitrogen by Distillation Spectrophotometry Using Nessler | 11 to 18 |
| Carbon (Total) by Direct Combustion–Thermal Conductivity | 19 to 29 |
| Total Chlorine and Fluorine by Pyrohydrolysis | 30 to 37 |
| Sulfur by Distillation Spectrophotometry | 38 to 46 |
| Plutonium Isotopic Analysis by Mass Spectrometry | 4 |
| Rare Earth Elements by Spectroscopy | 47 to 54 |
| Trace Elements by Carrier–Distillation Spectroscopy | 55 to 62 |
| (Alternative: Impurities by ICP-AES or ICP-MS) | |
| Impurity Elements by Spark-Source Mass Spectrography | 63 to 69 |
| Moisture by the Coulometric Electrolytic Moisture Analyzer | 70 to 77 |
| Total Gas in Reactor-Grade Plutonium Dioxide Pellets | 5 |
| Plutonium-238 Isotopic Abundance by Alpha Spectrometry | 3 |
| Americium-241 in Plutonium by Gamma-Ray Spectrometry | 2 |
| Rare Earths By Copper Spark-Spectroscopy | 78 to 87 |
| Plutonium Isotopic Analysis by Mass Spectrometry | 88 to 96 |
| Oxygen-To-Metal Atom Ratio by Gravimetry | 97 to 104 |
1.3The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Sections 6, 16.2.5, 44.7, 51.9 and 92.5.1.
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| ASTM C 1307 : 2015 : REDLINE | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 758 : 2004 : R2010 | Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Metal |
| ANSI N15.22 : 1987 | NUCLEAR MATERIALS - PLUTONIUM - BEARING SOLIDS - CALIBRATION TECHNIQUES FOR CALORIMETRIC ASSAY, |
| ANSI N15.35 : 1983 | NONDESTRUCTIVE ASSAY BY COUNTING PASSIVE GAMMA RAYS, GUIDE TO PREPARING CALIBRATION MATERIAL FOR, |
| ASTM C 698 : 2016 : REDLINE | Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Mixed Oxides ((U, Pu)O<inf>2</inf>) |
| ASTM E 343 : 1996 | Standard Test Method for Measuring Reaction Rates by Analysis of Molybdenum-99 Radioactivity From Fission Dosimeters (Withdrawn 2002) |
| ASTM C 1458 : 2016 : REDLINE | Standard Test Method for Nondestructive Assay of Plutonium, Tritium and <sup >241</sup>Am by Calorimetric Assay |
| ASTM C 758 : 2004 | Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Metal |
| ASTM C 1233 : 2015 : REDLINE | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 1307 : 2015 : REDLINE | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1235 : 1999 | Standard Test Method for Plutonium by Titanium(III)/Cerium(IV) Titration (Withdrawn 2005) |
| ASTM C 1625 : 2012 : REDLINE | Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances by Thermal Ionization Mass Spectrometry |
| ASTM C 1637 : 2013 : REDLINE | Standard Test Method for the Determination of Impurities in Plutonium Metal: Acid Digestion and Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) Analysis |
| ASTM E 116 : 1997 | Standard Practice for Photographic Photometry in Spectrochemical Analysis (Withdrawn 2002) |
| ASTM C 1672 : 2017 : REDLINE | Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer |
| ASTM C 1432 : 2015 : REDLINE | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1068 : 2015 : REDLINE | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1168 : 2015 : REDLINE | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
| ASTM E 115 : 1997 | Standard Practice for Photographic Processing in Optical Emission Spectrographic Analysis (Withdrawn 2002) |
| ASTM C 1268 : 2015 : REDLINE | Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry |
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